BPPTT - SF47, FERROUS AMMONIUM SULFATE SOLUTION (SU
- MSDS: BPPTT
- Manufacturer: FISHER SCIENTIFIC CHEMICAL DIV
- Product Name: SF47, FERROUS AMMONIUM SULFATE SOLUTION (SU
- National Stock Number: 6850-00N026770
Product Identification
Product ID:SF47, FERROUS AMMONIUM SULFATE SOLUTION (SU
MSDS Date:11/06/1991
FSC:6850
NIIN:00N026770
MSDS Number: BPPTT
Responsible Party
FAIR LAWN, NJ 07410
US
Emergency Phone: 201-796-7100/800-424-9300(CHEMTREC)
Info Phone: 201-796-7100 OR 201-796-7523
Cage: 1B464
Contractor
Telephone: 201-796-7100
Cage: 1B464
Ingredients
VASOMOTOR INSTABILITY/DILATED PUPILS & COMA MAY
RTECS: 9999999ZZ
IMMED, VICTIM MAY IMPROVE, BUT CYANOSIS, PULM EDEMA,
RTECS: 9999999ZZ
ANURIA, SHOCK, CONVULSIONS, COMA & DEATH MAY OCCUR
RTECS: 9999999ZZ
HEMORR HEPATIC NECROSIS, WHICH IS USUALLY
RTECS: 9999999ZZ
MAY OCCUR AFTER 4 WKS.PYLORIC STENOSIS & MILD
RTECS: 9999999ZZ
THROAT, ESOPHAGUS & ABDOM, VOMIT & DIARR OF CHARRED
RTECS: 9999999ZZ
ACIDEMIA, STOMATITIS, RAPID & WEAK PULSE, SHALLOW
RTECS: 9999999ZZ
& GASTRIC STENOSIS, PERFORATION OF GI
RTECS: 9999999ZZ
DENTAL ENAMEL.BRONCH SYMPS, RHINORRHEA, FREQUENT
RTECS: 9999999ZZ
DISTURB.ALKALINE DEPLETION OF BODY PRDCG AN
RTECS: 9999999ZZ
ING
RTECS: 9999999ZZ
2); (FERROUS AMMONIUM
CAS: 7783-85-9
RTECS: BR6500000
Fraction By Weight: 35%
OSHA PEL 1 (FE) MG/M3
ACGIH TLV: 1 (FE) MG/M3
(ORAL, RAT) 2140 MG/KG.
CAS: 7664-93-9
RTECS: WS5600000
Fraction By Weight: 1.5%
OSHA PEL 1 MG/M3
ACGIH TLV: 1 MG/M3; 3 STEL
EPA Report Quantity: 1000 LBS
DOT Report Quantity: 1000 LBS
WATER
CAS: 7732-18-5
RTECS: ZC0110000
Fraction By Weight: 63.5%
EVID OF CHEM REMAINS (@ LST 15-20 MIN).CONTINUE
RTECS: 9999999ZZ
(30-60 MIN). COVER W/STERILE BANDAGES. GET MD ATTN
RTECS: 9999999ZZ
MAINTAIN AIRWAY AND BLOOD PRESSURE. LAVAGE SHOULD BE
RTECS: 9999999ZZ
2ND & 3RD DEGREE BURNS W/NECROSIS.POSS CHARRING
RTECS: 9999999ZZ
INVOLVED.RSLTG WOUNDS MAY BE LONG IN HEALING & CAUSE
RTECS: 9999999ZZ
MAY CAUSE IRRIT.ING
RTECS: 9999999ZZ
BLURRED VISION & CONJUNCTIVAL CONGESTION.DEEP CORNEAL
RTECS: 9999999ZZ
W/SEV SEQUELAE.IRREPARABLE CORNEAL DAM & BLINDNESS
RTECS: 9999999ZZ
ABDOM PAIN,
RTECS: 9999999ZZ
INGEST.HEMATEMESIS, WATERY & THEN TARRY DIARR,
RTECS: 9999999ZZ
RAPID/WEAK/IMPERCEPTIBLE PULSE, HYPOTENSION, RAPID
RTECS: 9999999ZZ
Hazards
LD50 LC50 Mixture:SEE INGREDIENTS 1 & 2
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:ING 1:DUST MAY IRRITATE
NOSE & THROAT & CAUSE COUGHING/DFCLT BRTHG. ING 2:MISTS MAY CAUSE
MUC MEMB IRRIT. MAY CAUSE INCREASED PULM AIR FLOW RESISTANCE &
SUBSEQUENT SHALLOWER & MORE RAPID B RTHG, LOSS OF CONSCIOUSNESS
W/POSS DAM TO LUNG TISS, NASAL SECRETIONS, SNEEZING,
BURNING/TICKLING (EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SENSATION IN NOSE & THROAT &
RETROSTERNAL REGION, FOLLOWED BY COUGH, RESP DISTRESS,
TRACHEOBRONCHITIS. CONC MAY PRDCE BLOODY NASAL SECRETIONS & SPUTUM,
HEMATEMESIS GASTRITIS & PULM EDEMA. A S INGLE OVEREXP MAY LEAD TO
LARYNGEAL, TRACHEOBRONCHIAL & PULM EDEMA.SKIN:ING 1:MAY IRRIT.ING
2:MAY CAUSE SEV (ING 7)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
First Aid
First Aid:INHAL:MOVE TO FRESH AIR IMMED.IF BRTHG HAS STOPPED, GIVE ARTF
RESP, MAINTAIN AIRWAY & BLOOD PRESS & ADMIN O*2 IF AVAIL.KEEP
AFFECTED PERS WARM & @ REST.TREAT SYMPTOMATICALLY &
SUPPORTIVELY.ADMIN OF O* 2 SHLD BE PERFORMED BY QUALIFIED PERS.GET
MD ATTN IMMED.SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED.WASH AFFECTED
AREA W/SOAP/MILD DETERGENT & LG AMTS OF WATER UNTIL NO CHEM REMAINS
(@ LST (SUPP DATA)
Fire Fighting
Flash Point:NON-COMBUSTIBLE
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE. WATER SPRAY OR
REGULAR FOAM FOR LARGER FIRES. USE WATER SPRAY, FOG OR REGULAR
FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
.MOVE CNTNR FROM FIRE AREA IF CAN DO W/OUT RISK.DO NOT SCATTER
SPILLED MATL W/HIGH-PRESS WATER (SUPP DATA)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.
Accidental Release
Spill Release Procedures:STOP LEAK IF CAN DO IT W/OUT RISK. FOR SMALL
SPILLS: TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL AND PLACE
INTO CLEAN, DRY CONTAINERS FOR LATER DISPOSAL. KEEP UNNECESSARY
PEOPLE AWAY. ISOLATE HAZARD AREA AND DENY ENTRY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
Handling
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
Exposure Controls
Respiratory Protection:SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON
CONTAM LEVELS FOUND IN WORK PLACE, MUST BE BASED ON SPECIFIC OP,
MUST NOT EXCEED WORKING LIMITS OF RESPIRATOR AND MUST BE JOINTLY
APPROVED BY NIOSH/MSHA.F OR MORE SPECIFIC INFO CONT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION AND/OR GENERAL DILUTION
VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:PROTECTIVE GLOVES.
Eye Protection:CHEM WORK GOG & FULL LGTH FSHLD .
Other Protective Equipment:APPROP PROT (IMPERV) CLTHG & EQUIP TO PVNT
ANY POSS OF SKIN CONT.EYEWASH FOUNTAIN & QUICK DRENCH SHOWER W/IN
WORK AREA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:CONCENTRATE 0.1N. FIRE FIGHT PROC:STREAMS.DIKE
FIRE-CONTROL WATER FOR LATER DISP. FIRST AID PROC:15-20 MIN).CHEM
BURNS:COVER W/STERILE, DRY DRESSING, BANDAGE SECURELY, BUT NOT TOO
TIGHTLY. GET MD ATTN IMMED.EYE:WASH IMMED W/LG AMTS OF WATER,
OCCASIONALLY LIFTING LIDS, UNTIL NO (ING 4)
Chemical Properties
Spec Gravity:1.1
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:SOLUBLE
Appearance and Odor:PALE GREEN LIQUID
Stability
Stability Indicator/Materials to Avoid:YES
BASES, METALS, ORGANICS. FOR A COMPLETE LISTING OF MATERIALS TO AVOID
CONTACT NEHC .
Stability Condition to Avoid:NONE REPORTED.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC FUMES OF AMMONIA AND OXIDES OF NITROGEN AND SULFUR.
Disposal
Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL
REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.